“…However, due to the poor selectivity, difficulty in separation and recycling of these homogeneous catalysts, it is a matter of the utmost urgency to develop highly active, selective, and reusable heterogeneous catalysts for economical and eco‐friendly oxidation of alkenes. Many heterogeneous catalysts, including metal oxides, [34–40] polyoxometalates (POMs), [41–44] and zeolites‐, silica‐ or carbon materials‐supported metal nanoparticles [45–65] have been developed for the oxidation of styrene. However, the poor selectivity of many of these catalysts in converting styrene to benzaldehyde impels further development of catalysts.…”