Direct In Situ Vertical Growth of Interlaced Mesoporous NiO Nanosheets on Carbon Felt for Electrocatalytic Ammonia Synthesis

Abstract

Metal oxide nanomaterials directly grown on conductive substrates are optimal electrode materials because their structures allow for rapid ion and electron transport and thereby reduce internal resistance in the electrode. The development of such binder‐free, self‐supporting electrodes is of great significance for applications in electrocatalysis. In this work, a simple hydrothermal in situ self‐assembly reaction and annealing process was developed to prepare three kinds of nickel oxide @ carbon felt (NiO@CF) nanocomposites with different morphologies. The influence of different precipitators (strong or weak bases) on the morphology of the resulting nano‐sized nickel oxide nanocomposites was investigated. The microstructures of the NiO@CF samples were characterized with field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), X‐ray diffraction (XRD), and X‐ray photoelectron spectroscopy (XPS). When ammonia was used as the precipitator, NiO grew vertically on the surface of the carbon felt and formed a mesoporous nanosheet‐like structure (NiO NSs@CF). As an electrocatalytic nitrogen reduction reaction (e‐NRR) electrode, the NiO NSs@CF sample showed an excellent NH3 yield (71.3 μg h−1 mg−1cat.) and Faradaic efficiency (17.9 % at −0.5 V vs. RHE) in 0.1 M Na2SO4. The good performance was attributed to the vertical interleaved mesoporous sheet‐like structure (with the pore size of 15 nm and the thickness of ∼30 nm) and the relatively high concentration of oxygen vacancies. First‐principles calculations with strong on‐site Coulomb interactions demonstrated that the presence of oxygen vacancy on NiO sample leads to a significantly stronger N binding over the surface, benefiting for the nitrogen gas adsorption and reduction. The e‐NRR performance of this binder‐free, flexible electrode material is superior to that of other reported nickel‐based nanomaterials. This study highlights the potential of such binder‐free carbon felt electrodes for use in e‐NRR that could meet the needs of industrial production.

Double–single-atom MoCu-embedded porous carbons boost the electrocatalytic N2 reduction reaction

“…An H-shaped electrolytic cell was utilized to assess the eNRR performance of the material. Among them, the NH 3 yield rate of MoCu@C (52.4 μg h −1 mg cat −1 ) was 3.2 times more than that of Mo@C (16.3 μg h −1 mg cat −1 ), exceeding the rates of some recently reported materials (Pt/NiO, NiO@CF, NiO-NF) [38][39][40][41] (Fig. 5b and Table S1 †).…”

Flower-Like Ni–Mn Bimetallic Oxide-Based Nanosheets for Enhanced Electrocatalytic Nitrogen Reduction to Ammonia

“…As shown in Figure c, Ni 2p can be divided into Ni 2p 3/2 and Ni 2p 1/2 . The peaks with binding energies at 854.56 and 872.22 eV belong to Ni 2+ , while the peaks at 856.37 and 874.1 eV are attributed to Ni 3+ , and the peaks at 861.71 and 879.08 eV are satellite peaks (labeled as “Sat.”) Figure d shows the XPS spectrum of Mn 2p. , Considering that Mn 2p 1/2 with a binding energy close to Ni 2p is susceptible to interference, we mainly resolve Mn 2p 3/2 .…”

Emerging two-dimensional materials for the electrocatalytic nitrogen reduction reaction to yield ammonia

“…6b and c). Porous NiO nanosheets with oxygen vacancies on carbon felt (OVs-NiO NNs@CF) have been fabricated, 62 and were found to be effective at reducing the internal resistance of the electrode. Their work demonstrated a yield rate of 71.3 μg h −1 mg cat −1 and an FE of 17.9% at −0.5 V.…”