Direct, multielement determinations from cotton swipes via plate express microextraction coupled to an inductively coupled plasma mass spectrometer (μEx-ICP-MS)
Cameron J. Stouffer,
R. Kenneth Marcus
Abstract:Use of a microextraction device allows for ready sampling of solid substrates, such as cotton swipes, allowing transfer of sub-microgram quantities for multielement ICP-MS analysis.
“…9 The initial motivation for microextraction-ICP-MS was to eliminate bulk sample digestion, which can be a time consuming process, and instead directly sample the surface for the analysis of uranium, 7 plutonium, 10,11 and other trace elements. 12 Subsequent efforts explored extraction of solid uranium particulates from the surface, 13 with rapid isotopic determination.…”
A microextraction liquid sampling system coupled to a quadrupole inductively coupled plasma-mass spectrometer (ICP-MS) was utilized to spatially discern uranium particles, isotopically, on a cellulose-based swipe material (i.e., J-type swipe)....
“…9 The initial motivation for microextraction-ICP-MS was to eliminate bulk sample digestion, which can be a time consuming process, and instead directly sample the surface for the analysis of uranium, 7 plutonium, 10,11 and other trace elements. 12 Subsequent efforts explored extraction of solid uranium particulates from the surface, 13 with rapid isotopic determination.…”
A microextraction liquid sampling system coupled to a quadrupole inductively coupled plasma-mass spectrometer (ICP-MS) was utilized to spatially discern uranium particles, isotopically, on a cellulose-based swipe material (i.e., J-type swipe)....
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