Disilver(I) Coordination Complexes: Synthesis, Reaction Chemistry, and Their Potential Use in CVD and Spin‐Coating Processes for Silver Deposition

Copper(II) Schiff base complexes and their mixed thin layers with ZnO nanoparticles

“…The layers were amorphous, but small crystallites appeared in some places due to incomplete solidification of the complex solution during the spin coating process, as previously reported. 20,54 In the case of Cu(en(pyca) 2 )Cl 2 ] (1a)/Si and [Cu(en(dmbaH) 2 )Cl 2 ] (3a)/Si materials, the whole silicon surface was covered regularly with copper complexes (900, 1100 and 2000 rpm/min (1a)/Si and 1000, 1100 and 2000 rpm/min (3a)/Si). The EDS results confirmed the presence of copper (0.45% -900 rpm, 0.71% -1000 rpm and 0.47% -1100 rpm) in all (1a)/Si layers.…”

Crystal structure of (μ-1,4-dicarboxybutane-1,4-dicarboxylato)bis[bis(triphenylphosphane)silver(I)] dichloromethane trisolvate

“…Silver precursors [e.g. silver(I) carboxylates and silver(I) -diketonates] exhibit a wide range of applications, for instance the formation of thin, metallic layers by means of CVD (Chemical Vapour Deposition) or CCVD (Combustion Chemical Vapour Deposition) (Struppert et al, 2010;Jakob et al, 2006;Schmidt et al, 2005;Lang & Buschbeck, 2009;Lang, 2011;Lang & Dietrich, 2013;Chi & Lu, 2001), spin coating (Jakob et al, 2010) or inkjet printing (Jahn et al, 2010a,b;Gä bler et al, 2016). The respective silver layers show closed and homogeneous silver films and therefore possess a good conductivity.…”

Crystal structure ofcyclo-bis(μ4-2,2-diallylmalonato-κ6O1,O3:O3:O1′,O3′:O1′)tetrakis(triphenylphosphane-κP)tetrasilver(I)

“…These metal-organic complexes are of importance not only in the field of basic research but also in multipurpose applications including, for example, metallization processes for micro-and nano-structured new materials in electronic systems and devices (e.g. using chemical vapour deposition, CVD), since silver possesses the highest electrical conductivity of any element (Jakob et al, 2010;Lang & Dietrich, 2013), catalytic processes (Steffan et al, 2009) and their use in biological studies (Djokić, 2008;Zhu et al, 2003).…”