Abstract:As a part of our ongoing efforts, we have synthesized a new fluorescence probe p-C4A based on calix[4]arene substituted by 4-aminoquinoline moieties with amide linkage, which can selectively recognize Li+...
“…But among them, calixarene is the third generation supramolecular host compound after the crown ethers and cyclodextrins [ 29 ]. However, calixarenes and their derivatives have unique complexation abilities that allow for recognition of target molecules with high selectivity and efficient supramolecular recognition as well [ 30 , 31 ]. Moreover, they contain numerous cavity dimension with possibility to functionalization their upper and lower rim with different functional groups to improve its properties and to tailor their strong interaction with a target host molecules through different non-covalent interaction such as hydrogen bonding, π - π stacking, cation- π and CH-π interaction with the surface of target molecule [ [32] , [33] , [34] ].…”
“…But among them, calixarene is the third generation supramolecular host compound after the crown ethers and cyclodextrins [ 29 ]. However, calixarenes and their derivatives have unique complexation abilities that allow for recognition of target molecules with high selectivity and efficient supramolecular recognition as well [ 30 , 31 ]. Moreover, they contain numerous cavity dimension with possibility to functionalization their upper and lower rim with different functional groups to improve its properties and to tailor their strong interaction with a target host molecules through different non-covalent interaction such as hydrogen bonding, π - π stacking, cation- π and CH-π interaction with the surface of target molecule [ [32] , [33] , [34] ].…”
“…On the other hand, in the presence of Li + , the suppression of PET or in other words "PET-OFF" from aza-crown ether to NDI was occurred, which increased the uorescence emission. 93,115 Grabchev et al 116 synthesized a polyamidoamine dendrimer modied with 4-hexylamino-1,8-napthalimide as a uorescent and photochromic sensor for the detection of lithium ions. 117 In the alkaline media (in the presence of NaOH), deprotonation of the hexylamino groups at the C-4 position of the 1,8-naphthalimide structure was performed.…”
Application of lithium in portable electronic devices, medical field, catalysts, and so on has been increased in recent years because of unique properties of lithium. Therefore, detection and sensing of...
“…Our expertise in host-guest chemistry and uorescence sensors motivated us to explore novel synthetic uorescent host-guest systems for the purpose of detecting different molecular ions. [44][45][46][47][48][49][50][51][52] Following our seminal innovation of different receptors, we envisaged that substitution at the lowerrim of calix [4]arene with a cystamine linkage and coumarin uorophore will be a suitable approach for the recognition of CBF insecticide. This study proposes a scalable and extendable strategy for designing the highly efficient uorescence sensor CouC4S for the detection of CBF insecticide.…”
This research work presents a novel approach for the detection of carbofuran (CBF) insecticide, by systematically exploring calix[4]arene-derived fluorescence probe, CouC4S, functionalization with two coumarin-labelled cystamine linkage at the narrow...
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