Dissociative electron attachment to nitroethane: C2H5NO2

Abstract

Dissociative electron attachment to hexafluoroacetylacetone and its bidentate metal complexes M(hfac)2; M = Cu, Pd

Computational study on the reaction mechanism of the gas-phase atom-negative ion of S + NO2 −: comparative study of mechanism with S + O3 reaction as isoelectronic and isostructure systems

“…The negative DS values of steps (1) through (4) show that entropy (S) decreases in these steps, while it increases in remaining steps, (5) through (8). Finally, the 3 S ?…”

“…The formation of nitrite ion (NO 2 -) [8][9][10][11][12][13][14][15][16] as well as its reaction with other species is the subject of several investigations. Davidson et al [17] investigated the rate constant and the reaction heat (DH) of nitrite ion (NO 2 -) with N 2 O 5 experimentally.…”

Gas-phase clustering reactions of NO2−, C2H3NO2−, C2H4NO2−, C2H5NO2− and C2H5NO4− with C2H5NO2

“…of the electrons slowed down to energy of about 0.73 eV [14] by the gas in the reaction chamber. As discussed below, NO 2 − can also arise from the ion-molecule reaction of the O 2 − /C 2 H 5 NO 2 system.…”

“…As discussed below, NO 2 − can also arise from the ion-molecule reaction of the O 2 − /C 2 H 5 NO 2 system. Also, C 2 H 3 NO 2 − is produced by dissociative electron capture at ∼0 eV [14].…”

“…Dissociative electron attachment to C 2 H 5 NO 2 has been the subject of several investigations [12][13][14]. In a recent study, Märk and co-workers [14] reported the absolute partial cross-sections for the formation of eight fragment negative ions (NO 2 − , C 2 H 3 NO 2 − , O − , OH − , CN − , CNO − , HCN − and NO − ) by electron attachment to C 2 H 5 NO 2 in the gaseous phase under collision-free conditions.…”