Dissolution of copper and iron from automotive brake pad wear debris enhances growth and accumulation by the invasive macrophyte Salvinia molesta Mitchell

Shupert, Lindsay A.; Ebbs, Stephen D.; Lawrence, John H.; Gibson, David J.; Filip, Peter

doi:10.1016/j.chemosphere.2013.03.002

Cited by 15 publications

(6 citation statements)

References 42 publications

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“…indicating that road dust was not the source of d-Fe in coarse aerosol particles. This result is consistent with previous studies because Fesol% of debris of brake pads and tire wear is lower than 0.01% (Shupert et al, 2013;Halle et al, 2021).…”

Section: Coarse Aerosol Particlessupporting

confidence: 94%

“…coarse aerosol particles due to no correlation between the [d-Fe]/[d-Al] ratio and EF of Fe. This result is reasonable becausethe brake pads and tire wear debris are less than 0.01%(Shupert et al, 2013;Halle et al, 2021).3.6. The [d-Fe]/[d-Al] ratio in fine aerosol particles and their emissionsThe average [d-Fe]/[d-Al] ratio of fine aerosol particles (n = 45, average: 1.15 ± 0.803, range: 0.386-4.67) was higher than that of coarse aerosol particles and mineral dust (Figs.9a and 9b).…”

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confidence: 72%

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Measurement report: Stoichiometry of dissolved iron and aluminum as an indicator of the factors controlling the fractional solubility of aerosol iron: Results of the annual observations of size-fractionated aerosol particles in Japan

Sakaguchi

Yamakawa

Miyamoto

et al. 2023

Preprint

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Abstract. Atmospheric deposition of iron (Fe) in aerosol particles is enhanced primary production on the ocean surface, resulting in promoting the uptake of carbon dioxide into the surface seawater. Atmospheric deposition of iron (Fe) promotes primary production in the surface ocean, resulting in enhanced uptake of carbon dioxide into surface seawater. Since microorganisms in seawater utilize dissolved Fe (d-Fe) as a nutrient, the bioavailability of Fe in aerosol particles depends on its solubility. However, factors controlling fractional Fe solubility (Fesol%) in aerosol particles have not been fully understood. This study performed annual observations of Fesol% in size-fractionated (seven fractions) aerosol particles at Higashi-Hiroshima, Japan. In particular, the feasibility of the molar concentration ratio of d-Fe relative to dissolved Al ([d-Fe]/[d-Al]) as an indicator of the sources of d-Fe in aerosol particles because this ratio is likely dependent on the emission sources of Fe (e.g., mineral dust, fly ash, and anthropogenic Fe oxides) and their dissolution processes (proton-promoted and ligand-promoted dissolutions). Approximately 70 % of total Fe and dissolved Fe was present in coarse and fine aerosol particles, respectively, and the average Fesol% in fine aerosol particles (11.4 ± 6.97 %) was higher than that of coarse aerosol particles (2.19 ± 2.27 %). In addition, the average ratio of [d-Fe]/[d-Al] in coarse aerosol particles (0.408 ± 0.168) was lower than that in fine aerosol particles (1.15 ± 0.803). The range of [d-Fe]/[d-Al] ratios in the coarse aerosol particles (0.121–0.927) was similar to that obtained by proton-promoted dissolutions of mineral dust (0.1–1.0), indicating that d-Fe in coarse aerosol particles were derived from mineral dust. The [d-Fe]/[d-Al] ratios of aerosol particles ranged from 0.386 to 4.67, and [d-Fe]/[d-Al] ratios greater than 1.5 cannot be explained by proton-promoted dissolution and ligand-promoted dissolution (1.0 < [d-Fe]/[d-Al] < 1.5). The [d-Fe]/[d-Al] ratio correlated with the enrichment factor of Fe in fine aerosol particles (r: 0.505), indicating that anthropogenic Fe with a high [d-Fe]/[d-Al] ratio was the source of d-Fe in fine aerosol particles. The high [d-Fe]/[d-Al] ratio was attributed to Fe-oxides emitted from high-temperature combustions (high-temp-FeOx). Finally, the fraction of high-temp-FeOx to d-Fe in total suspended particulate (TSP) was calculated based on the [d-Fe]/[d-Al] ratio of aerosols and their emission source samples. As a result, the fraction of high-temp-FeOx to d-Fe in TSP varied from 1.48 to 80.7 %. The high fraction was found in summer when air masses originated from industrial regions in Japan. By contrast, approximately 10 % of d-Fe in the TSP samples collected in spring and during Asian dust events was derived from high-temp-FeOx, when air masses were frequently transported from East Asia to the Pacific Ocean. Thus, mineral dust is the dominant source of d-Fe in Asian outflow to the Pacific Ocean.

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Section: Coarse Aerosol Particlessupporting

confidence: 94%

mentioning

confidence: 72%

Measurement report: Stoichiometry of dissolved iron and aluminum as an indicator of the factors controlling the fractional solubility of aerosol iron: Results of the annual observations of size-fractionated aerosol particles in Japan

Sakaguchi

Yamakawa

Miyamoto

et al. 2023

Preprint

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“…Thus, road dust was not the source of d-Fe in coarse aerosol particles. This result is consistent with that of previous studies in which the Fe sol % of brake pads and tire wear debris was lower than 0.01 % (Shupert et al, 2013;Halle et al, 2021). The Fe sol % and Al sol % of coarse aerosol particles increased with the decrease in aerosol diameter (Fig.…”

Section: Coarse Aerosol Particlessupporting

confidence: 93%

Measurement report: Stoichiometry of dissolved iron and aluminum as an indicator of the factors controlling the fractional solubility of aerosol iron – results of the annual observations of size-fractionated aerosol particles in Japan

Sakata,

Sakaguchi,

Yamakawa

et al. 2023

Atmos. Chem. Phys.

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Abstract. The atmospheric deposition of iron (Fe) promotes primary production in the surface ocean, which results in the enhanced uptake of carbon dioxide into surface seawater. Given that microorganisms in seawater utilize dissolved Fe (d-Fe) as a nutrient, the bioavailability of Fe in aerosol particles depends on its solubility. However, the factors controlling fractional Fe solubility (Fesol %) in aerosol particles have not been fully understood. This study performed annual observations of the total and dissolved metal concentrations in size-fractionated (seven fractions) aerosol particles at Higashi-Hiroshima, Japan. The feasibility of the molar concentration ratio of d-Fe relative to dissolved Al ([d-Fe] / [d-Al]) as an indicator of sources of d-Fe in aerosol particles was investigated because this ratio is likely dependent on the emission sources of Fe (e.g., mineral dust, fly ash, and anthropogenic Fe oxides) and their dissolution processes (proton- and ligand-promoted dissolutions). Approximately 70 % of the total Fe in total suspended particulates (TSPs) was present in coarse aerosol particles, whereas about 70 % of d-Fe in TSPs was mainly found in fine aerosol particles. The average Fesol % in fine aerosol particles (11.4 ± 7.0 %) was higher than that of coarse aerosol particles (2.19 ± 2.27 %). In addition, the average ratio of [d-Fe] / [d-Al] in coarse aerosol particles (0.408 ± 0.168) was lower than that in fine aerosol particles (1.15 ± 0.80). The range of [d-Fe] / [d-Al] ratios in the coarse aerosol particles (0.121–0.927) was similar to that obtained by proton-promoted dissolution of mineral dust (0.1–1.0), which indicates that the d-Fe in coarse aerosol particles was derived from mineral dust. The [d-Fe] / [d-Al] ratios of fine aerosol particles ranged from 0.386 to 4.67, and [d-Fe] / [d-Al] ratios greater than 1.50 cannot be explained by proton- and ligand-promoted dissolutions (1.00 < [d-Fe] / [d-Al] < 1.50). The [d-Fe] / [d-Al] ratio correlated with the enrichment factor of Fe in fine aerosol particles (r: 0.505), which indicates that anthropogenic Fe with a high [d-Fe] / [d-Al] ratio was the source of d-Fe in fine aerosol particles. The high [d-Fe] / [d-Al] ratio was attributed to anthropogenic Fe oxides emitted from high-temperature combustions. Finally, the fraction of anthropogenic Fe oxides to d-Fe in TSPs was calculated based on the [d-Fe] / [d-Al] ratio of aerosols and their emission source samples. As a result, the fraction of anthropogenic Fe oxides to d-Fe in TSPs varied from 1.48 % to 80.7 %. A high fraction was observed in summer when air masses originated from industrial regions in Japan. By contrast, approximately 10 % of d-Fe in the TSPs collected in spring and during Asian dust events was derived from anthropogenic Fe oxides when air masses were frequently transported from East Asia to the Pacific Ocean. Thus, mineral dust was the dominant source of d-Fe in Asian outflow to the Pacific Ocean.

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“…Experiments were performed on rainy days to reduce the effect of resuspended traffic-generated particles. The number of particles per m3 measured was 1.7 107 and a maximum of 410 nm [265]. A significant variation in concentrations determined on the brake and the front of the car was noted.…”

Section: Field Studiesmentioning

confidence: 99%

Tribo-mechanical performance of brake composite material: A comprehensive review

Dhinakaran¹,

Katiyar

Ruggiero

2023

Tribology - Materials, Surfaces & Interfaces

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The composite materials are fabricated by combining various ingredients to make higher material properties as required by various industries. The primary classification of composites is based on their build ingredients, such as binder, fibre, reinforcement and fillers. The characteristics of individual ingredients influenced the properties of composites. Further, friction materials are those composite materials efficiently used in vehicles' braking.Researchers have tried the various formulations of friction materials because it is very significant to study the mechanism and material characteristics due to the safety measures of vehicles. The current study examines the various brake composite materials' characteristics and their mechanical and tribological performance in this article. The tribological study includes the various terminologies used in friction and wear using pin-ondisc, dynamometer, field studies, etc. The effects of numerous elements impacting the wear of frictional materials are given, and the tribological performances of used friction materials are given the utmost attention.

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Dissolution of copper and iron from automotive brake pad wear debris enhances growth and accumulation by the invasive macrophyte Salvinia molesta Mitchell

Cited by 15 publications

References 42 publications

Measurement report: Stoichiometry of dissolved iron and aluminum as an indicator of the factors controlling the fractional solubility of aerosol iron: Results of the annual observations of size-fractionated aerosol particles in Japan

Measurement report: Stoichiometry of dissolved iron and aluminum as an indicator of the factors controlling the fractional solubility of aerosol iron: Results of the annual observations of size-fractionated aerosol particles in Japan

Measurement report: Stoichiometry of dissolved iron and aluminum as an indicator of the factors controlling the fractional solubility of aerosol iron – results of the annual observations of size-fractionated aerosol particles in Japan

Tribo-mechanical performance of brake composite material: A comprehensive review

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