With the development of intelligent vehicle technology, the demand for advanced driver assistant systems kept increasing. To improve the performance of the active safety systems, we focused on right-turning vehicle’s collision warning and avoidance. We put forward an algorithm based on Monte Carlo simulation to calculate the collision probability between the right-turning vehicle and another vehicle (or pedestrian) in intersections. We drew collision probability curves which used time-to-collision as the horizontal axis and collision probability as the vertical axis. We established a three-level collision warning system and used software to calculate and simulate the collision probability and warning process. To avoid the collision actively when turning right, a two-stage braking strategy is applied. Taking four right-turning collision conditions as examples, the two-stage braking strategy was applied, analysing and comparing the anteroposterior curve diagram simultaneously to avoid collision actively and reduce collision probability. By comparison, the collision probability 2 s before active collision avoidance was more than 80% and the collision probability may even reach 100% in certain conditions. To improve the active safety performance, the two-stage braking strategy can reduce the collision probability from exceeding 50% to approaching 0% in 2 s and reduce collision probability to less than 5% in 3 s. By changing four initial positions, the collision probability curve calculation algorithm and the two-stage braking strategy are validated and analysed. The results verified the rationality of the collision probability curve calculation algorithm and the two-stage braking strategy.