Distance learning: an interdisciplinary experiment on Rayleigh scattering

Abstract

As a result of social distancing measures in response to the Covid-Sars 2 pandemic, our school sent chemistry kits to the students’ homes for remote experimentation. This allowed the performance of ∼25 experiments per person in each of the Fall 2020 and Spring 2021 semesters in an elective chemistry course. Students were requested to design some experiments of their own and then have the entire group reproduce them. One such experiment consisted of the anodic indirect electrogeneration of colloidal sulfur by solution acidification to produce thiosulfate disproportionation. This was evidenced by the well-known Rayleigh scattering phenomenon. Here, the trajectory and polarization state of light are modified by its interaction with a medium containing particles of smaller diameter than the wavelengths of incident light. If white light interacts with this medium, the smaller wavelengths (e.g., blue, violet) are radially scattered while the longer wavelengths (e.g., orange, red) pass through the suspension. Such scattering is responsible for beautiful sunsets and blue skies and is produced here by an indirect electrochemical process that generates colloidal sulfur. Students evidence the scattering of light shone from simple cell phone flashlights. The entire procedure is performed in a 2-h class session. Key student outcomes are presented.

Distance learning of introductory electrochemistry and corrosion: home experimentation

“…As part of our elective course, students were also requested to design experiments on their own and have the entire group reproduce them (previous teacher’s approval). This led us to several successful experiences which were then published, including the fabrication of a fuel cell from solar electrolysis [ 1 ], bismuth plating by galvanic displacement [ 3 ], tin electroplating [ 4 ], homemade colloidal silver [ 5 ], indirect electrolytically induced Rayleigh scattering [ 6 ], and the homemade CO 2 capture and conversion [ 7 ].…”