Distribution and Biodegradation Potential of Buried Oil on a Coastal Headland Beach

Abstract

Buried and surface MC252 oil from the intertidal on a coastal headland beach was sampled using a randomized block methodology. Weathering indices contrasting alkylated 3- (phenanthrenes) and 4-ring (chrysene) PAH concentrations were computed based on analyses of these samples. Buried oil was detected at a frequency of 18% and, of those samples, 29% had indices indistinguishable from oil sampled near the wellhead indicating that PAH weathering was not occurring. These samples with persistent PAHs were associated with one or more conditions in the beach profile: located at or near the depth of the water table, nearest to the shoreline, or within a thicker oil mat deposit. Surface oil samples, consisting of oil:sand aggregates recently washed in by the surf, had a higher percentage (81%) of oil with weathering indices indicating persistence. These observations, coupled with measurements of biogeochemical analyses on the beach from other studies, suggest that insufficient oxygen in the nearshore environment of these coastal headlands creates conditions for PAH persistence over time frames of years to decades.