2023
DOI: 10.1021/acsmaterialslett.3c00254
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Diverse Self-Assembly and Xenon Binding from a Single Mesomeric Macrocycle Component

Abstract: Xenon binding has received considerable interest, but effective hosts remain rare, and the majority of assembly-type hosts are barely explored. Here, we report the synthesis, selfassembly, and xenon inclusion behavior with a homemade mesomeric bisurea−bisthiourea macrocycle. Compared to its racemic counterparts as recently investigated, the single mesomeric macrocycle forms even more comprehensive dimerization assemblies. From the single macrocycle component, up to two pairs of enantiomeric homochiral dimeric … Show more

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