2024
DOI: 10.1021/jacs.4c12958
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Dual-Mode Emission and Solvent-Desorption Dependent Kinetic Properties of Crystalline-State Chemiluminescence Reaction of 9-Phenyl-10-(2-phenylethynyl)anthracene Endoperoxide

Norihisa Yamasaki,
Chihiro Matsuhashi,
Hidehiro Uekusa
et al.

Abstract: The chemiluminescence (CL) feature and reactivity of the aromatic endoperoxide 9-phenyl-10-(2-phenylethynyl)anthracene endoperoxide (PPEA-O 2 ) were investigated in the crystalline state. For this, PPEA-O 2 crystals were prepared using dichloromethane and n-hexane. These crystals exhibited an α-phase structure containing n-hexane as a crystal solvent. The crystal structure of nonperoxidic anthracene (i.e., PPEA) was also confirmed. After optimizing heating conditions to 120 °C for the thermolytic reaction of P… Show more

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