As carbon monoxide within the oceanic surface layer is produced by solar radiation, diluted by mixing, consumed by biota, and outgassed to the atmosphere, it exhibits a diurnal cycle. The effect of dilution and mixing on this cycle is examined using a simple model for production and consumption coupled to three different mixed layer models. The magnitude and timing of the peak concentration, the magnitude of the average concentration, and the air-sea flux are considered. The models are run through a range of heating and wind stress and compared to experimental data reported by Kettle [1994]. The key to the dynamics is the relative size of four length scales; Dmix, the depth to which mixing occurs over the consumption time; L, the length scale over which production occurs; L out, the depth to which the mixed layer is ventilated over the consumption time; and Leorap , the depth to which the diurnal production can maintain a concentration in equilibrium with the atmosphere. If Dmi x >> L, the actual model parameterization can be important. If the mixed layer is maintained by turbulent diffusion, D mi x can be substantially less than the mixed layer depth. If the mixed layer is parameterized as a homogeneous slab, D mi x is equivalent to the mixed layer depth. If Dmi x > Lout, production is balanced by consumption rather than outgassing. The ratio between D mi x and Leonap determines whether the ocean is a source or a sink for CO. The main thermocline depth H sets an upper limit for D mi x and hence D mix/L , D mix/Lout, and D mix/Lcomp. The models are run to simulate a single day of observations. The mixing parameterization is shown to be very important, with a model which mixes using smallscale diffusion producing markedly larger surface concentrations than models which homogenize the mixed layer completely and instantaneously. Paper number 96JC00463. 0148-0227/96/96JC-00463509.00 forcing. If it is O(1 d-•) or smaller, the maximum concentrations are seen at the end of the day.In the presence of mixing, however, the picture becomes more complicated. The importance of the optical properties of the water, the timing of the maximum concentration, and the partition between gas exchange and consumption as sink terms can all depend on the mixing. This paper uses the diurnal cycle of carbon monoxide (CO) in order to attack the following four questions:1. When is dilution important in determining the surface concentration and flux of a photochemically produced trace species such as CO?2. How sensitive is the diurnal cycle to the exact parameterization of the optics, consumption, and outgassing, and how does such sensitivity depend on the mixing? 3. How sensitive are the results to different parameterizations of the dilution? One question of particular interest is the difference between slab models, which homogenize the mixed layer instantaneously and completely, and eddy viscosity models which require some time for the mixed layer to become homogenized. 4. When can a tracer such as CO be used to improve understanding of the...