With the vigorous development of the automobile industry, the rubber industry has also made continuous progress. As necessary mixing equipment in the rubber industry, the internal mixer is required to undertake a lot of constant work for a long time, which inevitably causes wear to the internal mixer. On the one hand, the wear of the metal on the end face of the internal mixer will lead to an increase in the gap between the inner mixing chamber and the end face, which will lead to material leakage, affect the material ratio of the rubber mixture, and ultimately affect the performance of the rubber mixture. On the other hand, the wear of the end metal of the internal mixer is an increasing process, and the tiny metal particles of the end metal will be incorporated into the rubber mix along with the mixing process, affecting the performance of the rubber mix. At the same time, the disassembly and repair of the internal mixer are complex, and the end face maintenance is difficult. Therefore, finding a kind of end face metal with good wear resistance, long service life, and no influence on rubber compound performance is essential. This paper takes the end face metal of the internal mixer with severe wear as the research object. The wear degree of the metal after friction between MCYD-4 alloy, YW-15 alloy, wear-resistant stainless steel, tungsten carbide alloy, and the rubber compound is compared. The changes in the properties of the compounds after rubbing were investigated. The study found that the tensile tear properties, wet skid resistance, and rolling resistance of NR/BR composites differed when different end-face metals were selected for mixing, but the gap was small. When the end-face metal is YW-15 alloy, the NR/BR composites have the best dispersibility, the most robust tensile tear performance, the best wet-skid resistance, and minor rolling resistance. When the end face metal is the other three alloys, the physical and mechanical properties of the NR/BR composites are reduced to different extents. In this paper, starting from the actual working conditions, considering both abrasive wear and corrosive wear, the friction and wear between the rubber compound and the four kinds of metals commonly used on the end face of the internal mixer are studied. The metal that has little effect on the performance of the rubber compound and is the most wear-resistant was found. This paper is of great significance for improving production efficiency and prolonging the life of the internal mixer.