“…The changes of the XRF parameters for elements in alloys can be explained as a result of changes in the valance electronic configurations or charge transfer effect. Recently, several researches have been carried out the alloying effect on various parameters such as various physical properties of 3d transition metals alloys (Chattopadhyay & Manna, 2002;Chen et al, 2004Chen et al, , 2009Diercks & Loomis, 1986;Evtikhin, Lyublinski, Vertkov, Votinov, & Dedyurin, 2002;Kim, Kim, Choi, & Jeong, 2006, 2008Lai, Chen, Tsai, & Ding, 2003;Sadrnezhaad & Selahi, 2004;Santos, de Castro, Ishikawa, & Ticianelli, 2007;Takahashi, Ohnuki, Kinoshita, & Nakahigashi, 1991;Wang & Wang, 2009;Wei, Changlong, Tao, & Xiaohua, 2007;Yao, Li, Wee, Chai, & Pan, 2001). And also, alloying effect on K XRF crosssection and K-shell fluorescence yield for Cr, Ni, Al elements in Cr x Ni 1-x and Cr x Al 1-x alloys (Büyükkasap, 1998a, b) and for Ni in NieSi alloys (Kalayci et al, 2005) have been reported.…”