Effect of binary antioxidant heterodimer properties on the oxidation stability enhancement of palm oil biodiesel

Hamdani, Ali; Sutanto, Hery; Siregar, Ali Rimbasa; Lucia, Anda; Nasikin, Mohammad

doi:10.1063/5.0013648

Cited by 1 publication

(2 citation statements)

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“…Despite all that, the addition of binary proved significance effect on biodiesel, with biodiesel with binary antioxidants took the lead by little difference in comparison to B100-bi+GMS. According to a study by Hamdani et al (2020), the formation of a heterodimer interaction between two antioxidants results in the generation of a more effective and superior antioxidant compound [20].…”

Section: Effect Of Various Additive Addition To Kinematic Viscosity A...mentioning

confidence: 99%

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Binary Effect of Tertiary Butylhydroquinone and Butylated Hydroxytoluene Additives with The Addition of Glycerol Monostearate to Improve Oxidative Stability of Palm Oil-Based Biodiesel

Yusri,

Chuaca,

Sutanto

2024

E3S Web Conf.

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Biodiesel is a renewable and environmentally friendly alternative to conventional diesel fuel. However, like any fuel, biodiesel is subject to oxidation, which can negatively impact its quality and performance when kept for long-term. The addition of binary antioxidants such as TBHQ:BHT had been proven to improve oxidation stability of biodiesel. Combining surfactant such as GMS into single antioxidant had been proven to solve its insolubility issue. However, the implementation of mixing binary antioxidants and surfactant has not been done yet. Therefore, this research analyzed the effect of single antioxidant, binary antioxidants, and binary antioxidants with GMS (100 ppm) addition into biodiesel and biodiesel blend B35. The effect was observed within 8 weeks storage period. The result showed that B35 did not have any significant impact. While in pure biodiesel samples, B100-bi and B100-bi+GMS had a slight difference in the results of oxidative parameters. B100-bi showed the best result in induction period and kinematic viscosity. Rancimat test showed 170 hours for B100-bi and 168 hours for B100-bi+GMS. While B100-bi+GMS indicated as the best additives in term of acid number, iodine value, and dispersion test. Hence, the addition of surfactant into binary antioxidants showed similar performance with B100-bi but with slightly better solubility.

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Section: Effect Of Various Additive Addition To Kinematic Viscosity A...mentioning

confidence: 99%

“…The combination of TBHQ and BHT creates a synergistic effect and is able to enhance the oxidative stability of biodiesel [19]. The addition by binary antioxidants could outperformed single antioxidants in terms of induction time [11,20,21].…”

Section: Introductionmentioning

confidence: 99%