Effect of bismuth excess on the energy storage performance of 0.5Na0.5Bi0.5TiO3–0.5SrTiO3 ceramics

Chen, Peng; Yang, Chuanhua; Cai, Jiali; Wang, Ziyang; Zhang, Leiyang; Shi, Wengjing; Jing, Jiayi; Wei, Fangbin; Yan, Yan; Yu, Kun

doi:10.1088/2053-1591/ab56f1

Cited by 12 publications

(4 citation statements)

References 44 publications

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“…It is difficult to make transparent ceramics by ordinary sintering methods. The sintering process of KNN ceramic is relatively harsh, resulting in low energy storage characteristics of ceramics. − To improve this situation and enhance the energy storage density ( W ), the breakdown electric field ( E b ) of ceramics should be increased as much as possible and the remanent polarization strength ( P r ) should be reduced. − Recent studies have pointed out that the transparency of ceramic is related to the grain size and pore defects of samples, and grain size ( G ) is considered to play a leading role. − In general, the relationship between E b and G can be expressed as , E normalb ∝ 1 G …”

Section: Introductionmentioning

confidence: 99%

Design of a KNN-BZT Ceramic with High Energy Storage Properties and Transmittance under Low Electric Fields

et al. 2023

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With the advancement of science and technology, single-function ceramics have been difficult to meet the rapid development of electronic components. It is of great significance to find and develop multifunctional ceramics with excellent performance and environmental friendliness (such as good energy storage and transparency). Especially, the realization of its excellent performance under low electric fields has more reference and practical value. In this study, by Bi(Zn 0.5 Ti 0.5 )O 3 (BZT) modification in (K 0.5 Na 0.5 )NbO 3 (KNN), reducing grain size, and increasing band gap energy, the purpose of improving energy storage performance and transparency has been achieved under low electric field. The results show that the submicron average grain size decreased to 0.9 μm and the band gap energy (E g ) increased to 2.97 eV for 0.90KNN-0.10BZT ceramics. The transparency is up to 69.27% in the near-infrared region (1344 nm) and the energy storage density is 2.16 J/cm 3 under 170 kV/cm. Moreover, the 0.90KNN-0.10BZT ceramic exhibits a power density (P D ) of 17.50 MW/cm 3 and the stored energy can be discharged in 1.60 μs at 140 kV/cm. This revealed a potential application of KNN-BZT ceramic as an energy storage and transparent capacitor in the electronics industry.

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Section: Introductionmentioning

confidence: 99%

Design of a KNN-BZT Ceramic with High Energy Storage Properties and Transmittance under Low Electric Fields

et al. 2023

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“…Ma et al 27 partially replaced NBT‐24ST by doping antiferroelectric AgNbO 3 (AN) and obtained an excellent energy storage performance ( W rec = 2.03 J/cm 3 ) under 120 kV/cm. Chen et al 28 studied 0.5NBT‐0.5ST by adding excessive Bi 2 O 3 , which reduced grain size effectively and improved energy storage properties. Yang et al 11 prepared 0.5SrTiO 3 ‐0.5(0.95Na 0.5 Bi 0.5 TiO 3 ‐0.05BaAl 0.5 Nb 0.5 O 3 ) ceramics and obtained a high energy storage density of 1.89 J/cm 3 .…”

Section: Introductionmentioning

confidence: 99%

Enhanced energy storage properties of Sr(Ti _0. ₅ Zr ₀ _.5 ) O ₃ modified (Na _0. ₅ Bi ₀ _.5 )
Zhang
¹
,
Dai
²
,
Pan
³

et al. 2022
Intl J of Energy Research
13
0
2
0
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Summary With the rapid development of electronic industry, the miniaturization and integration of components have become an irreversible development trend, which puts forward high requirements for lead‐free ceramic materials with excellent recoverable energy storage density and efficiency. In addition, it is also a great challenge to sustain excellent energy storage performance under different environmental conditions. In this work, a combined design strategy was proposed to induce polar nano regions and reduce grain size by introducing SrTi0.5Zr0.5O3 (STZ). The addition of STZ reduced the grain size to submicron level, accompanied by relaxation enhancement. The high energy storage properties (Wrec = 1.85 J/cm3, η = 65.92%) were achieved in 0.80Bi0.5Na0.5TiO3‐0.20SrTi0.5Zr0.5O3 (BNT‐STZ) ceramics at 150 kV/cm. Excellent temperature stability (40°C‐160°C) and frequency stability (1‐500 Hz) of energy storage performance have been obtained under 100 kV/cm, with the fluctuations below 8%. Importantly, A high power density of 3.64 MW/cm3 and a transitory discharge time (t0.9 ~ 0.632 μs) were achieved for 0.80BNT‐0.20STZ ceramic under 160 kV/cm. These characteristics indicate that 0.80BNT‐0.20STZ ceramic is expected to be applied in high‐power equipment. Highlights A combined design strategy was proposed to induce polar nano regions and reduce grain size by introducing STZ. 0.80BNT‐0.20STZ ceramic possesses a recoverable energy density of 1.85 J/cm3 and efficiency of 65.92%. 0.80BNT‐0.20STZ ceramic exhibits good electrical stability in wide frequency (1‐500 Hz) and temperature range (40‐160°C). A high power density (PD) of 3.64 MW/cm3 and a transitory discharge time (t0.9 ~ 0.632 μs) can be achieved.

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“…However, it has already been shown to have harmful effects on humans when handled and also on the environment during processing. It is because of the above-mentioned that many researchers have focused on alternative ceramic systems to replace PZT while retaining their optimum properties [9][10][11][12][13][14][15]. In previous works we were able to synthesize an NBT ceramic with high purity [16]; the NBT ceramic is an interesting option for the substitution of PZT ceramics due to its synthesis processes and good properties.…”

Section: Introductionmentioning

confidence: 99%

Study of the Effect of Pva Incorporation on the Particle Size of Ceramics With NBT Structure Without Structural Lead

León¹,

Gonzalez²,

Serna³

2022

JHSR

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In this work, we report the particle size and compositional results obtained during the incorporation of polyvinyl alcohol in the regrind of an advanced ceramic with NBT (Bi0.5-xNa0.5+x) TiO3 structure, which was synthesized by high-energy mechanical milling. Mechanical milling proved to be a suitable process to synthesize this type of material by obtaining a high purity of the phase. The effect of incorporating polyvinyl alcohol (PVA) as a milling aid after the thermal process was studied. As a result, a particle radius reduction of 48 % was obtained, reaching nanometric sizes. In the study by infrared spectroscopy, it was observed that PVA did not generate bonds with the ceramic, so it is not an agent that modifies the structure of the ceramic.

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Effect of bismuth excess on the energy storage performance of 0.5Na_0.5Bi_0.5TiO₃–0.5SrTiO₃ ceramics

Cited by 12 publications

References 44 publications

Design of a KNN-BZT Ceramic with High Energy Storage Properties and Transmittance under Low Electric Fields

Design of a KNN-BZT Ceramic with High Energy Storage Properties and Transmittance under Low Electric Fields

Enhanced energy storage properties of Sr(Ti _0. ₅ Zr ₀ _.5 ) O ₃ modified (Na _0. ₅ Bi ₀ _.5 )
Zhang
¹
,
Dai
²
,
Pan
³

et al. 2022
Intl J of Energy Research
13
0
2
0
View full text Add to dashboard Cite

Study of the Effect of Pva Incorporation on the Particle Size of Ceramics With NBT Structure Without Structural Lead

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Effect of bismuth excess on the energy storage performance of 0.5Na0.5Bi0.5TiO3–0.5SrTiO3 ceramics

Cited by 12 publications

References 44 publications

Design of a KNN-BZT Ceramic with High Energy Storage Properties and Transmittance under Low Electric Fields

Design of a KNN-BZT Ceramic with High Energy Storage Properties and Transmittance under Low Electric Fields

Enhanced energy storage properties of Sr(Ti 0. 5 Zr 0 .5 ) O 3 modified (Na 0. 5 Bi 0 .5 ) Zhang1, Dai2, Pan3 et al. 2022Intl J of Energy Research13020View full textAdd to dashboardCite

Study of the Effect of Pva Incorporation on the Particle Size of Ceramics With NBT Structure Without Structural Lead

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Effect of bismuth excess on the energy storage performance of 0.5Na_0.5Bi_0.5TiO₃–0.5SrTiO₃ ceramics

Enhanced energy storage properties of Sr(Ti _0. ₅ Zr ₀ _.5 ) O ₃ modified (Na _0. ₅ Bi ₀ _.5 )
Zhang
¹
,
Dai
²
,
Pan
³

et al. 2022
Intl J of Energy Research
13
0
2
0
View full text Add to dashboard Cite