Effect of Fe Doping on The Structural, Morphological, Optical, Magnetic and Dielectric Properties of BaSnO3

Abstract

Doping at the possible A or B site in the ABO3 perovskite can alter the structural, morphological and optical properties of the compounds. Perovskite alkaline earth stannate BaSnO3 doped with Fe resulted in BaSn1-xFexO3 compounds having different concentrations (x=0.00, 0.01, 0.02, 0.03, 0.05 and 0.07) were prepared by solid-state method. The Rietveld analyzes were performed to determine the phase purity and the changes in structural parameters. Morphological analysis identifies the formation of hexagonal nanorods with doping. The non linear optical property of the prepared samples shows optical power limiting behaviour. Magnetic property signifies the existence of ferromagnetic order and EPR studies reveal the possible ferromagnetic ordering of Fe doped samples. Dielectric loss decreases with Fe doping and has a gradual decrease in the higher frequency regime and has applications in high frequency devices.