Effect of MgO/h-BN Composite Support on Catalytic Activity of Ba-Ru/MgO/h-BN for Ammonia Synthesis

Yang, Xiaolong; Tang, Liping; Xia, Chungu; Xiong, Xia; Mu, Xindong; Hu, Bin

doi:10.1016/s1872-2067(11)60352-5

Cited by 12 publications

(2 citation statements)

References 34 publications

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“…Researchers are therefore seeking to improve the activity of the catalyst by modifying the MgO support. 20–22…”

Section: Introductionmentioning

confidence: 99%

“…Researchers are therefore seeking to improve the activity of the catalyst by modifying the MgO support. [20][21][22] In recent years, there has been growing interest in altering the properties of supports by introducing defects on their surfaces. [23][24][25][26][27][28][29] However, limited research has been conducted on the modication of MgO supports through surface defects.…”

Section: Introductionmentioning

confidence: 99%

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Regulating oxygen vacancies by Zn atom doping to anchor and disperse promoter Ba on MgO support to improve Ru-based catalysts activity for ammonia synthesis

Chen,

He,

Lei

et al. 2024

RSC Adv.

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“…Researchers are therefore seeking to improve the activity of the catalyst by modifying the MgO support. 20–22…”

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Regulating oxygen vacancies by Zn atom doping to anchor and disperse promoter Ba on MgO support to improve Ru-based catalysts activity for ammonia synthesis

Chen,

He,

Lei

et al. 2024

RSC Adv.

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Hydrogen Nanoreservoirs Made of Boron Nitride

Chkhartishvili

2014

Nanomaterials for Environmental Protection

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The Journey toward Low Temperature, Low Pressure Catalytic Nitrogen Fixation

Shi

Zhang

Waterhouse

et al. 2020

Advanced Energy Materials

158

101

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Ammonia and its derived products are vital to modern societies. Artificial nitrogen fixation to ammonia via the Haber–Bosch process has been employed industrially for over 100 years. However, the Haber–Bosch process is energy intensive and not sustainable in its current form as it uses hydrogen sourced from steam methane reforming to reduce N2. The roadmap to sustainable NH3 production demands the discovery of novel approaches for nitrogen fixation under near ambient conditions that preferably use water as the reducing agent. Over the last decade, great efforts have been made to develop catalysts capable of N2 fixation under mild reaction conditions, using strategies such as low temperature thermal catalysis, nonthermal plasma catalysis, enzymatic catalysis, photocatalysis, and electrocatalysis to generate ammonia and other valuable nitrogen‐containing chemicals. In parallel with catalytic performance studies, researchers have also placed emphasis on the mechanistic understanding of natural and artificial nitrogen fixation catalysts. In this work, the various routes now being explored for nitrogen fixation are summarized. The different dinitrogen activation and hydrogenation pathways are described, whilst describing key advances made to date on the journey toward near ambient ammonia synthesis. Key obstacles that need to be overcome to attract industry interest are also discussed.

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Effect of MgO/h-BN Composite Support on Catalytic Activity of Ba-Ru/MgO/h-BN for Ammonia Synthesis

Cited by 12 publications

References 34 publications

Regulating oxygen vacancies by Zn atom doping to anchor and disperse promoter Ba on MgO support to improve Ru-based catalysts activity for ammonia synthesis

Regulating oxygen vacancies by Zn atom doping to anchor and disperse promoter Ba on MgO support to improve Ru-based catalysts activity for ammonia synthesis

Hydrogen Nanoreservoirs Made of Boron Nitride

The Journey toward Low Temperature, Low Pressure Catalytic Nitrogen Fixation

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