The main development direction of energy efficiency technologies in construction is the creation of various materials with complex structures and unique strength, thermal properties, and other properties. The aerogel is a material with high porosity and excellent thermal insulation properties. This paper provides state-of-the-art aerogel applications for the additive manufacturing of energy-efficient buildings. This work provides the experimental and numerical assessment results of the thermal conductivity of aerogel-enhanced blanket, the experimental assessment results of thermal performance of aerogel-enhanced building structure, the experimental assessment results of the aerogel application as a mixture powder component of the concrete mixture to printing buildings, and the experimental assessment results of the aerogel application as a parget powder component. Experimental results show the effect of aerogel powder component application: thermal conductivity decreased by 25%.