An attempt has been made to study the multidimensional instability of dust-ion-acoustic (DIA) solitary waves (SWs) in magnetized multi-ion plasmas containing opposite polarity ions, opposite polarity dusts and nonthermal electrons. First of all, we have derived ZakharovKuznetsov (ZK) equation to study the DIA SWs in this case using reductive perturbation method as well as its solution. Small-k perturbation technique was employed to find out the instability criterion and growth rate of such a wave which can give a guideline in understanding the space and laboratory plasmas, situated in the D-region of the Earth's ionosphere, mesosphere, and solar photosphere, as well as the microelectronics plasma processing reactors.