Three d 10 coordination polymers formulated as [Zn(L1) 2 (mip)] n (1), [Zn(L1)(2,6-ndc)] n (2) and [Cd(L2) 0.5 (bpdc)] n (3) (L1 = 1,1 0 -(1,3-propanediyl)bis(thiabendazole), L2 = 1,1 0 -(1,6-hexanediyl)bis(thiabendazole), H 2 mip = 5-methylisophthalic acid, 2,6-H 2 ndc = 2,6-naphthalenedicarboxylic acid, H 2 bpdc = 4,4 0 -biphenyldicarboxylic acid) were hydrothermally synthesized. Complexes 1-3 were characterized by elemental analysis, IR spectroscopy, X-ray powder diffraction analysis, and single crystal X-ray diffraction. Complexes 1 and 2 present different chain structures, both of them are extended into 2D supramolecular architectures via C-HÁÁÁO hydrogen bonds, while 3 is a threefold interpenetrating three-dimensional framework with binodal 4,4-connected mog topology. The thermal stability, UV-visible spectroscopy and luminescence properties of complexes 1-3 were also examined. Furthermore, complex 3 exhibits relatively positive catalytic activity towards the degradation of methyl orange in a Fenton-like process.