“…Group theory predicts that there are two E 1 , two E 2 , two A 1 and two B 1 symmetry phonon modes in wurtzite structure crystals, and among these modes the two B 1 modes are not Raman active , the others can be observed in the Raman spectrum [9] . Therefore, the frequencies of the fundamental optical modes in ZnO can be present as E 2 (low)=101 cm -1 , E 2 (high) = 437 cm −1 , A 1 (TO) = 380 cm −1 , A 1 (LO) =574 cm −1 , E 1 (TO) = 407 cm −1 , E 1 (LO) = 583 cm −1 [10] . The Raman spectrum of the Ag doped ZnO microrods is shown in Fig.…”