2017
DOI: 10.17221/6/2016-swr
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Effect of temperature and soil pH on the sorption of ibuprofen in agricultural soil

Abstract: Hiller E., Šebesta M. (2017): Effect of temperature and soil pH on the sorption of ibuprofen in agricultural soil. Soil & Water Res., 12: 78−85.Besides many natural factors, soil pH and temperature can have significant effects on the sorption of pharmaceuticals in soils. This is the first study, which aimed to evaluate the effect of soil pH and temperature on the sorption of ibuprofen in soil. Sorption-desorption experiments at 20°C indicated weak retention of ibuprofen in the soil. Sorption of ibuprofen in th… Show more

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Cited by 18 publications
(8 citation statements)
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“…Depending on recent studies, the high level of many of pharmaceuticals in plant roots than plant leaves might be attributed to several factors, such as the concentration of pharmaceuticals in soil solution, pharmaceutical octanol-water partition coefficient, lipophilicity and physico-chemical characteristics of both pharmaceutical and soil (28)(29)(30). However, the lipophilic compounds could be taken up by plant roots through active and passive transport in high level in comparison to plant leaves.…”
Section: Results and Discussion: Uptake Of Test Pharmaceuticals By Plantmentioning
confidence: 99%
“…Depending on recent studies, the high level of many of pharmaceuticals in plant roots than plant leaves might be attributed to several factors, such as the concentration of pharmaceuticals in soil solution, pharmaceutical octanol-water partition coefficient, lipophilicity and physico-chemical characteristics of both pharmaceutical and soil (28)(29)(30). However, the lipophilic compounds could be taken up by plant roots through active and passive transport in high level in comparison to plant leaves.…”
Section: Results and Discussion: Uptake Of Test Pharmaceuticals By Plantmentioning
confidence: 99%
“…The water solubility is corrected following Trapp and Matthies ( 1998 ) and K OW by calculating it as the fraction of octanol solubility and water solubility at pH 7. The protolysation calculations in the model were validated by building a Level I model environment simulating IBU partitioning pH dependency measurements by Hiller and Šebesta ( 2017 ) and comparing the results. Although low pH partitioning differed greatly, the results at pHs ≥ 5.8 agreed well, suggesting that the calculations are adequate for environmental applications.…”
Section: Methodsmentioning
confidence: 99%
“…O coeficiente de partição octanol--água (K ow ), indicador da hidrofobicidade de um contaminante, sofre uma redução com o aumento da temperatura, de magnitude variável de acordo com o tipo de composto (HULSCHER & CONERLISSEN 1996, COLOMBANO et al 2020. A solubilidade e o K ow estão diretamente associados à sorção do contaminante no meio; dessa forma, em temperaturas maiores os contaminantes tendem a ser menos retidos por sorção, sendo mais facilmente removidos do solo (BAHADUR et al 1997, TSE & LO 2002, BORRIRUKWISITSAK et al 2012, HILLER & ŠEBESTA 2017. Assim como a solubilidade, a taxa de difusão molecular FIGURA 1 -Faixas da temperatura de ebulição para diferentes classes de contaminantes.…”
Section: Mecanismos De Remoção Dos Contaminantes Pela Temperaturaunclassified
“…A biodegradação dos contaminantes também pode ser favorecida com o aumento da temperatura, durante ou após o processo de remediação (HERON et al 2005). O aquecimento do solo em baixas temperaturas (aproximadamente 70 °C) pode favorecer as taxas de biodegradação de contaminantes como organoclorados e hidrocarbonetos de petróleo (HERON et al 2005, HORST et al 2018.…”
Section: Mecanismos De Remoção Dos Contaminantes Pela Temperaturaunclassified
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