Polyurethane is a promising topcoat in anticorrosive coating system. As a topcoat, the study on improving its weathering resistance is significative. In this work, we present an anticorrosive filler, named GOFA based on p‐fluoroaniline chemical modified graphene oxide, and explored the potential of GOFA to improve the weatherability and corrosion resistance of polyurethane coatings. The results of the comprehensive experimental studies showed that the addition of 0.5 wt.% GOFA leaded to an improvement in the hydrophobicity of the polyurethane coating and the composite coating exhibits an excellent shielding effect against corrosive media. At the same time, the ultraviolet aging resistance the GOFA modified polyurethane composite coating also showed satisfactory results. It is inspired that adding a small amount of GOFA can make the composite polyurethane coating have excellent anti‐corrosion performance and weather resistance.