Corrosion is generally an undesirable phenomenon in most engineering applications. The effects of micro-arc oxidation (MAO) coating on Al alloy on the galvanic corrosion performance have been studied. The surface micro-structures were characterized using scanning electron microscope (SEM) and metallographic microscope before and after corrosion. Electrochemical studies on the corrosion behaviors have been reported by using open circuit potential (OCP) and potentiodynamic polarization (PDP) measurements in a slurry solution. All measurements were consistent with each other and showed that the MAO coating can significantly reduce the corrosion rate of Al alloy. A model for elucidating corrosion mechanism and corrosion process of the MAO coating on Al alloy is proposed.