Effects of doping on the transport properties of CoSb3

Abstract

Effects of doping on the transport properties of CoSb3 have been systematically investigated using Ni, Pd, and Pt as donor impurities. It is shown that the Hall mobility, the Seebeck coefficient, and the electrical conductivity depend strongly not only on the carrier concentration but also on these donor impurities. Our theoretical analysis suggests that the electron effective mass and the conduction band deformation potential are significantly affected by both the doping levels and the donor impurities. These doping effects in CoSb3 can be attributed to (1) the changes in the electronic structure with doping and (2) the specific nature of the conduction band structure, in particular, the nonparabolicity of the band which can be explained in terms of a two-band Kane model. The observed changes in the electronic properties with doping are also consistent with the predictions of a recent band structure calculation of CoSb3. On the other hand, the lattice thermal conductivity decreases markedly with increasing carrier concentration, and is almost independent of the donor impurities. Our analysis based on the Debye model indicates that the coupling of the point-defect (alloy) scattering with the electron-phonon scattering plays an important role in reducing the lattice thermal conductivity in heavily doped n-type CoSb3. The effects of doping on the phonon scattering are also discussed on the basis of a model calculation as a function of the electronic properties and the impurity properties (atomic mass and size). As a result, it is found that the strength of the electron-lattice interaction (the electron-phonon coupling), which is closely related to the effective mass and the deformation potential, is an important factor affecting the scattering of phonons as well as charge carriers in heavily doped n-type CoSb3.

Effect of Yb Filling on Thermoelectric Properties of Ge-Substituted CoSb<SUB>3</SUB> Skutterudites

“…[14][15][16] The hole effective mass for ptype Co 4 Ge 0:5 Sb 11:5 agrees well with the extrapolation of the dependence for p-type CoSb 3 . On the other hand, it is clearly noted that the electron effective mass for n-type Yb y Co 4 Ge 0:5 Sb 11:5 is larger than that for n-type Yb y Co 4 Sb 12 at similar carrier concentrations.…”

“…24 m À3 ). 14,15) The carrier conductivity changes from p-type to n-type when the Yb composition increases from y ¼ 0:1 to 0.2 since the electrons are donated from Yb ions. In the case of Yb y Co 4 Sb 12 , the change of conductivity occurs at a very small amount of Yb addition.…”

“…Acoustic phonon scattering is commonly cited as the dominant scattering mechanism near room temperature in filled and unfilled skutterudites. 1,14,15) We first calculated the reduced Fermi energy from the experimental Seebeck coefficient data using…”

Thermoelectric properties of semi conducting compound Sb71.22Co2.97Fe20.77Ce5.04

“…As the lattice thermal conductivity decreases with the increasing content of Fe and Ce, The thermal conductivity of p-type skutterudite (Sb 71.22 Co 2.97 Fe 20.77 Ce 5.04 ) is lower than of the thermal conductivity of n-type (Co 23.87 Sb 73.88 Pd 1.125 Te 1.125 ) at ambient temperature [17]. This reduction of lattice thermal conductivity (k L ) can be attributed to that Fe would enter the compound substitutionally, replacing Co [18,19]. Indeed the Fe presence introduces an additional disorder what increase the phonon scattering.…”

Electrodeposition of Ni and Te‐doped Cobalt Triantimonide in Citrate Solutions

“…This is an excellent example of the PGEC concept in which phonon scattering centers can be introduced in the unit cell to lower the lattice thermal conduc-tivity. Most of today s research focuses on reducing lattice thermal conductivity by introducing large heavy atoms into the skutterudite structure [2,4], which can be achieved by doping.…”