The impingement of liquid sprays on hot walls is used extensively in both spray-cooling systems and in combustor fuel injection applications. At low and moderate wall temperatures, the secondary size distributions have been reported in the literature. For high wall superheat conditions, particularly for real multicomponent fuels, this secondary size distribution has received less attention. Understanding the resultant size distribution for a spray-wall impact is key to capturing vaporization and local mixture for fuel-spray impingement. In this study, single drop impacts for a range of single-component (n-decane) and multicomponent jet fuel (F-24) are characterized through dual-view imaging. Secondary droplets are captured for impact Weber numbers of 100–600 and wall temperatures spanning the nucleate and film boiling (Leidenfrost) regimes. Imaging through a transparent sapphire substrate is used to capture the impact phenomena and impact-induced breakup of impacting drops. We report empirical correlations for the secondary droplet size for single-component (n-decane) and multicomponent (F-24) liquid fuels with varying wall temperature to provide validation datasets for spray-wall simulations.