“…Derivatization of PBA to these chalcogenides can be performed by both hydrothermal and thermal procedures, while suldes have also been achieved by liquid methods. 23,67,71,72,75,76,83,89,90 In the thermal method, H 2 S can be directly used, or sulfur powder can be heated to produce sulfur vapour and combined with H 2 gas to diffuse as H 2 S gas in the PBA structure. Sometimes sulfur or sulfur-containing additives are incorporated in the PBA particles in pretreatment steps, acting as a source of sulfur during the heat treatment.…”