Efficient and stable tripodal Phosphine-Controlled Pd-Catalyst for anti-Markovnikov hydroaminocarbonylation of alkenes with aromatic amines

Chen, Xiao‐Chao; Lan, Tian; Zhu, Jun; Ying, Sibin; Shi, Guang-Hui; Zhao, Kai‐Chun; Guo, Lin; Lu, Yong; Liu, Ye

doi:10.1016/j.jcat.2023.01.022

Journal of Catalysis

2023

DOI: 10.1016/j.jcat.2023.01.022

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Efficient and stable tripodal Phosphine-Controlled Pd-Catalyst for anti-Markovnikov hydroaminocarbonylation of alkenes with aromatic amines

Xiao‐Chao Chen

Tian Lan

Jun Zhu³

et al.

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2024

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Cited by 7 publications

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Cobalt‐Catalyzed Intramolecular Markovnikov Hydrocarbonylation of Unactivated Alkenes via Hydrogen Atom Transfer

Jiang,

Li,

Xiao

et al. 2024

Angewandte Chemie

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A cobalt‐catalyzed intramolecular Markovnikov hydroalkoxycarbonylation and hydroaminocarbonylation of unactivated alkenes has been developed, enabling highly chemo‐ and regioselective synthesis of α‐alkylated γ‐lactones and α‐alkylated γ‐lactams in good yields. The mild reaction conditions allow use of mono‐, di‐ and trisubstituted alkenes bearing a variety of functional groups. Preliminary mechanistic studies suggest the reaction proceeds through a CO‐mediated hydrogen atom transfer (HAT) and radical‐polar crossover (RPC) process, in which a cationic acylcobalt(IV) complex is proposed as the key intermediate.

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Cobalt‐Catalyzed Intramolecular Markovnikov Hydrocarbonylation of Unactivated Alkenes via Hydrogen Atom Transfer

Jiang,

Li,

Xiao

et al. 2024

Angewandte Chemie

View full text Add to dashboard Cite

show abstract

Cobalt‐Catalyzed Intramolecular Markovnikov Hydrocarbonylation of Unactivated Alkenes via Hydrogen Atom Transfer

Jiang,

Li,

Xiao

et al. 2024

Angew Chem Int Ed

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Adducts of t-butyl-substituted diphosphines with triflic acid: Synthesis, characterization and application to Pd-catalyzed methoxycarbonylation-aminolysis tandem reaction

Chen,

Shi,

Jing

et al. 2024

Journal of Catalysis

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Efficient and stable tripodal Phosphine-Controlled Pd-Catalyst for anti-Markovnikov hydroaminocarbonylation of alkenes with aromatic amines

Cited by 7 publications

References 35 publications

Cobalt‐Catalyzed Intramolecular Markovnikov Hydrocarbonylation of Unactivated Alkenes via Hydrogen Atom Transfer

Cobalt‐Catalyzed Intramolecular Markovnikov Hydrocarbonylation of Unactivated Alkenes via Hydrogen Atom Transfer

Cobalt‐Catalyzed Intramolecular Markovnikov Hydrocarbonylation of Unactivated Alkenes via Hydrogen Atom Transfer

Adducts of t-butyl-substituted diphosphines with triflic acid: Synthesis, characterization and application to Pd-catalyzed methoxycarbonylation-aminolysis tandem reaction

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