Efficient multicomponent synthesis of propargylamines catalyzed by copper nanoparticles supported on metal-organic framework derived nanoporous carbon

Cheng, Saisai; Shang, Ningzhao; Cheng, Feng; Gao, Shutao; Wang, Chun; Wang, Zhi

doi:10.1016/j.catcom.2016.10.030

Cited by 57 publications

(16 citation statements)

References 35 publications

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“…Moreover, MOFs have aroused interest in heterogeneous catalysis owing to their high surface areas, uniform pores, and chemical tunability 30,31 . Postsynthetic modification of MOFs has recently been employed as a general approach for incorporating a wide range of functional groups into MOFs 32–37 .…”

Section: Introductionmentioning

confidence: 99%

Anchorage of Au3+ into Modified Isoreticular Metal–Organic Framework-3 as a Heterogeneous Catalyst for the Synthesis of Propargylamines

Liu

Tai

Zhou

et al. 2017

Sci Rep

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Postsynthetic modification of metal-organic framework is a general and practical approach to access MOF-based catalysts bearing multiple active sites. The isoreticular metal–organic framework-3 (IRMOF-3) was modified with lactic acid through condensation reaction of the carboxyl group of lactic acid and amino group present in IRMOF-3 frameworks. Au3+ was subsequently anchored onto the metal–organic framework IRMOF-3 using postsynthetic modification. The synthezized IRMOF-3-LA-Au (LA = lactic acid) was characterized by powder X-ray diffraction, N2 adsorption-desorption, infrared spectroscopy, liquid-state nuclear magnetic resonance, thermogravimetric analysis, H2-temperature programmed reduction, transmission electro microscopy, and inductively coupled plasma–optical emission spectrometry. IRMOF-3-LA-Au acted as an efficient heterogeneous catalyst in the synthesis of propargylamines by three-component coupling reaction of aldehyde, alkyne, and amine. Moreover, the catalyst is applicable to various substituted substrates, including aromatic and aliphatic aldehydes, alkyl- and aryl-substituted terminal alkynes, and alicyclic amines. In addition, the catalyst can be easily separated from the mixture and can be reused for four consecutive cycles.

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Section: Introductionmentioning

confidence: 99%

Anchorage of Au3+ into Modified Isoreticular Metal–Organic Framework-3 as a Heterogeneous Catalyst for the Synthesis of Propargylamines

Liu

Tai

Zhou

et al. 2017

Sci Rep

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“…Cheng et al reported the successful deposition of Cu nanoparticles on MOF-5-C that was fabricatedb yd irect carbonizationo f MOF-5 withouta ny additional carbon sources. [55] The surface area of MOF-5-C (2,524 m 2 g À1 )w as higher than that of Cu@MOF-5-C (2039 m 2 g À1 ). In the A 3 -coupling (aldehydealkyne-amine) reaction, Cu@MOF-5-C had ah igher catalytic activity,e ven with as maller surface area.…”

Section: Introduction Of Heteroatoms Into Mof-derived Carbonsmentioning

confidence: 90%

Metal–Organic Framework (MOF)‐Derived Nanoporous Carbon Materials

Marpaung

Kim

Khan

et al. 2019

Chemistry An Asian Journal

141

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Metal–organic framework (MOF)‐derived nanoporous carbon materials have attracted significant interest due to their advantages of controllable porosity, good thermal/chemical stability, high electrical conductivity, catalytic activity, easy modification with other elements and materials, etc. Thus, MOF‐derived carbons have been used in numerous applications, such as environmental remediations, energy storage systems (i.e. batteries, supercapacitors), and catalysts. To date, many strategies have been developed to enhance the properties and performance of MOF‐derived carbons. Herein, we introduce and summarize recent important approaches for advanced MOF‐derived carbon structures with a focus on precursor control, heteroatom doping, shape/orientation control, and hybridization with other functional materials.

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“…[166] One method to obtain metal-NP-supported MOFs is through post synthesis impregnation and such systemshave shown good potential in heterogeneous catalysis. [167] Nanoscale periodicity of the pores in MOFs with metal core showedh igh optical andm agnetic properties together with strong X-ray attenuation,s uggesting them as ideal candidate for assembling multifunctional components. [168] To date many chemical impregnations trategies are explored to decorate metal NPs on organic-inorganic hybrid supports.…”

Section: Organic-inorganic Hydrids Upportsmentioning

confidence: 99%

Supported Porous Nanomaterials as Efficient Heterogeneous Catalysts for CO₂ Fixation Reactions

Bhanja

Modak

Bhaumik

2018

Chemistry A European J

116

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CO is a major greenhouse gas responsible for global warming and can act as an abundant and inexpensive C1 source for enhancing the chain length/functionalization of a wide range of reactive organic molecules. It is moderately reactive, nontoxic and renewable. Thus, CO fixation reactions are important to meet the global challenges, that is, to mitigate the concentration of CO in the atmosphere through its fruitful utilization, which is of great interest from economic and environmental perspectives. Various metallic nanoparticles as well as metal oxides can be supported over high surface area porous materials and the resulting nanomaterial can act as heterogeneous and reusable solid catalyst for CO fixation reactions for the synthesis of a large number of fuels, natural products agrochemicals, and pharmaceutical compounds. Here we present an overview of the recent progress as well as promising future of metal/metal oxide nanoparticles supported over porous nanomaterials as heterogeneous catalysts for a wide spectrum of these CO fixation reactions.

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Efficient multicomponent synthesis of propargylamines catalyzed by copper nanoparticles supported on metal-organic framework derived nanoporous carbon

Cited by 57 publications

References 35 publications

Anchorage of Au3+ into Modified Isoreticular Metal–Organic Framework-3 as a Heterogeneous Catalyst for the Synthesis of Propargylamines

Anchorage of Au3+ into Modified Isoreticular Metal–Organic Framework-3 as a Heterogeneous Catalyst for the Synthesis of Propargylamines

Metal–Organic Framework (MOF)‐Derived Nanoporous Carbon Materials

Supported Porous Nanomaterials as Efficient Heterogeneous Catalysts for CO₂ Fixation Reactions

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Efficient multicomponent synthesis of propargylamines catalyzed by copper nanoparticles supported on metal-organic framework derived nanoporous carbon

Cited by 57 publications

References 35 publications

Anchorage of Au3+ into Modified Isoreticular Metal–Organic Framework-3 as a Heterogeneous Catalyst for the Synthesis of Propargylamines

Anchorage of Au3+ into Modified Isoreticular Metal–Organic Framework-3 as a Heterogeneous Catalyst for the Synthesis of Propargylamines

Metal–Organic Framework (MOF)‐Derived Nanoporous Carbon Materials

Supported Porous Nanomaterials as Efficient Heterogeneous Catalysts for CO2 Fixation Reactions

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Supported Porous Nanomaterials as Efficient Heterogeneous Catalysts for CO₂ Fixation Reactions