Efficient one‐pot tandem conversion of saccharides to 2,5‐dimethylfuran by adjusting the wettability of 2DMOF catalysts

Abstract

One-pot multiple tandem synthesis of DMF from biomass saccharides including monosaccharides, disaccharides, and polysaccharides is of great importance for biomass fuels and chemicals. Due to the complexity of reactions, current catalytic systems often suffer from inferior activity, low yield, and harsh reaction conditions.Here, a Pd-supported hydrophobic acidic 2DMOF (Pd/NUS-PhSO 3 H-Ph) was first prepared by continuous grafting of benzenesulfonic acid and tert-butylbenzene