Doped Polyaniline, FT-IR studied, A.C Electrical Propertiesed Polyaniline was prepared in different acidic medium at room temperatuer. The out put of polymerization was characterization by FT-IR. The A.C electrical properties were studied. A.C conductivity σac(ω) is found to vary as ω s in the frequency range (100Hz-10MH), the value of (S) was found to be less than unity (S<1), the dielectric constant (ε1) and dielectric loss (ε2) have been determined for bulk polyaniline. Both (ε1) and (ε2) decrease with the increase of the frequency.