Electroanalysis of thiocyanate using a novel glassy carbon electrode modified by aryl radicals and cobalt tetracarboxyphthalocyanine

Preparation and characteristic of cobalt phthalocyanine modified carbon paste electrode for bisphenol A detection

“…Previous reports on the interaction of CoPc with oxidation substrate proposed the involvement of the Co(III)/Co(II) redox process [22,33,47]. In our work, Co(III)/ Co(II) redox potential is observed in the range of 0.1-0.2 V ( Fig.…”

“…So, the Co in CoPc complexes can coordinate axially with some molecules of substrates, which involve coordination atom, such as phenolic complexes [22], sulfhydryl compounds [32], nitrite [33], amine compounds [46], and thiocyanate [47]. Moreover, CoPc complexes can also coordinate with solvent molecules, such as H 2 O [48], DMF [48], and DMSO [49].…”

Electrode Modification Using Alkyne Manganese Phthalocyanine and Click Chemistry for Electrocatalysis

“…The bare GCE surface was grafted (Scheme A) by electrodeposition and scanning from +0.5 V to −1 V for 5 cycles in a solution of 0.1 mM 4‐azidobenzenediazonium tetrafluoroborate (containing 0.01 M TBABF 4 in 96 : 4 CANACN : HCl (1 M)) following reported methods . Between each step of grafting, the electrode was rinsed thoroughly via ultrasoncication for 5 min with milli‐Q water, to give grafted‐GCE.…”

Reactivity trends of Fe phthalocyanines confined on graphite electrodes in terms of donor–acceptor intermolecular hardness: Linear versus volcano correlations

“…In the other mechanisms (see mechanism B, Ref. [22]) we proposed that electron transfer could also occur in a concerted fashion with direct bond forming [21,22,38].…”