Electrocatalysis of Oxygen Evolution Reaction Promoted by CoNiMn Films Synthesized by Electrodeposition

Abstract

Recently, efforts have been made to address the environmental damage caused by fossil-fuel-based primary energy sources. Interest in efficient technologies for converting and storing energy using renewable sources, especially sunlight, has increased, with the aim of replicating the natural photosynthesis process. However, artificial photosynthesis faces challenges with unfavorable kinetics and thermodynamics, requiring the use of stable catalysts for the hydrogen evolution (HER) and oxygen evolution (OER) reactions to generate H 2 and O 2 , respectively. OER is the most prohibitive of the half-reactions by the highly sluggish kinetics. Mixed oxides, particularly those based on first-row transition metals, have shown promising results as catalysts for the OER. This work reports the synthesis of CoNiMn oxide via electrodeposition on fluoride tin oxide followed by electrochemical activation. This approach seeks to explore the synergistic effect between the elements and to produce a catalyst with superior efficiency and stability for the electrocatalysis of the OER compared to the monometallic and bimetallic oxides. The CoNiMn film was structurally and electrochemically characterized. The electrodeposited CoNiMn hybrid films demonstrated low overpotentials compared with standard OER electrocatalysts, with CoNiMn films outperforming all single and bimetallic oxide films. The activated CoNiMn film required an overpotential of 100 mV at 10 mA cm −2 (430 mV at 25 mA cm −2 ) and Tafel slope of 58 mV dec −1 . The film was active for 15 h at 100 mA cm −2 and showed no significant change in morphology and structure after the chronopotentiometry, indicating that it is a promising and cost-effective alternative to enhance the OER activity using abundant elements.