Electrochemical and Crystallographic Aspects of Lead Granular Growth

Comparative Morphological and Crystallographic Analysis of Electrochemically- and Chemically-Produced Silver Powder Particles

“…The crystals with well-defined (111) planes as those observed during electrocrystallization of lead [29] can be easily identified among the powder particles obtained from the nitrate electrolyte (Figure 2d,e). The powder particles obtained from this electrolyte showed the strong (111) preferred orientation.…”

Fundamental aspects of lead electrodeposition processes: Nucleation and growth

“…Većina od ovih granula je sa dobro definisanim kristalnim ravnima i mogu se označiti kao (poli)čestice. Ravni dvojnikovanja se lako uočavaju u većini od ovih čestica [22]. Ove forme granula se formiraju u početnim stupnjevima taloženja na svim prenapetostima i iz svih tipova elektrolita.…”

“…Ove forme granula se formiraju u početnim stupnjevima taloženja na svim prenapetostima i iz svih tipova elektrolita. Tokom taloženja iz razblaženih elektrolita i na nižim prenapetostima, njihov oblik opstaje duže vreme, dok pri taloženju iz koncentrovanih elektrolita i na višim prenapetostima, rast većine od njih je jako brzo zaustavljen [22]. …”

Preparation of porous lead from shape-controlled PbO bulk by in situ electrochemical reduction in ChCl–EG deep eutectic solvent

“…7b-b ). According to references [13,15], the controllable parameters enables electrodeposition technique to be a versatile and facile method to fabricate microstructure with novel architectures. The morphologies generally include cubic, octahedral, or truncated versions of these shapes and anisotropic ones such as dendrites, wires, whiskers, fibers, rods, stripes, and so on [43,44].…”

“…The advantages of this way as compared with others are low capital investment and costs, as well as uniform pore size and high porosity of products [3,4]. The electrolytes for lead electroplating are usually acidic such as hydrofluoride [1], pyrophosphate [10], fluorborate [11], fluorosilicate [12], bromide [13], iodide [13], nitrate [14,15], acetate [16] chloride [17], etc. Besides, alkaline solutions are also widely used in lead electrodeposition process [18,19].…”