Electrochemical Organic Synthesis

Xu, Hai-Chao

doi:10.1055/s-0040-1720081

Synthesis

2023

DOI: 10.1055/s-0040-1720081

|View full text |Cite

Electrochemical Organic Synthesis

Hai-Chao Xu

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

References 28 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

[1,2]-Retro-Brook rearrangement induced by electrochemical reduction of silyl enolates

Kinoshita,

Maejima,

Niki

et al. 2024

Bulletin of the Chemical Society of Japan

View full text Add to dashboard Cite

Electrochemical reduction of the trimethylsilyl enolates of alkyl aryl ketones induces retro-Brook rearrangement to provide 1-aryl-1-trimethylsilylalkan-1-ols. The transformation proceeds through a sequence of 1) single-electron reduction of the silyl enolate, 2) protonation with a phenol, 3) another single-electron reduction to form siloxy-substituted benzylic anion, and 4) the pivotal retro-Brook rearrangement.

show abstract

[1,2]-Retro-Brook rearrangement induced by electrochemical reduction of silyl enolates

Kinoshita,

Maejima,

Niki

et al. 2024

Bulletin of the Chemical Society of Japan

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Electrochemical Organic Synthesis

Cited by 1 publication

References 28 publications

[1,2]-Retro-Brook rearrangement induced by electrochemical reduction of silyl enolates

[1,2]-Retro-Brook rearrangement induced by electrochemical reduction of silyl enolates

Contact Info

Product

Resources

About