Electron density manipulation in rhodium(I) phosphine complexes: structure of acetylacetonatocarbonylferrocenyl- diphenylphosphinerhodium(I)

Crystal structure of (Z)-4,4,4-trifluoro-3-((2-hydroxyphenyl)amino)-1- (thiophen-2-yl)but-2-en-1-one, C14H10F3NO2S

“…The b-ketoiminate complexes have drawn interest because of their higher thermalstability [7]than the b-diketonate analogues and their versatility, by changing the imine substituents,f or tailoring their reactivity and volatility [7][8][9][10][11].The condensation of equimolar amounts of the 1,3-diketone and 2-aminophenol in ethanol afforded the phenolimino-ketone ligand. The spectroscopic data well accounted for the enol form of the ligand [15].…”

Crystal structure of dichlorido bis(2-methylbenzothiazole-κ 1N)palladium( II) chloride, C16H14Cl2N2PdS2

“…the oxygen atom with sulphur atom to study the effect on coordination behaviour of these ligands [7][8][9][10]. However the cyclization process to form benzothiazoles often prevents the formation of these types of ligands [11][12][13].…”

Tetrakis(8-quinolinolato-κ2N,O)hafnium(IV) dimethylformamide solvate monohydrate

“…is also utilized in the extraction and separation industry (Van Aswegen et al, (1991); Steyn et al, (1992Steyn et al, ( , 1997; Otto et al, (1998); Roodt & Steyn, (2000);Brink et al, (2010)). This study forms part of an ongoing research project that investigates the formation of Hf(IV) and Zr(IV) complexes with various bidentate ligands with possible applications in the mentioned industries (Zherikova et al, (2005(Zherikova et al, ( , 2006(Zherikova et al, ( , 2008; Steyn et al, (2008); Viljoen et al, (2008Viljoen et al, ( , 2009aDemakopoulos et al, (1995); Lewis & Fay (1974) and Calderazzo et al (1998).…”

“…For hafnium and zirconium -diketonato complexes, see: Viljoen et al (2008Viljoen et al ( , 2009b; Demakopoulos et al (1995); Zherikova et al (2005Zherikova et al ( , 2006Zherikova et al ( , 2008; Steyn et al (2008); Calderazzo et al (1998). For acetylacetone in separation chemistry, see: Van Aswegen et al (1991); Steyn et al (1992Steyn et al ( , 1997; Otto et al (1998); Roodt & Steyn (2000); Brink et al (2010).…”