2024
DOI: 10.1155/2024/1969686
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Electron Spin Resonance Spin Probe Technique for Investigating Non‐TEMPO Radicals Dispersed in Nanospaces of a Crystalline Zn Complex

Hirokazu Kobayashi,
Kento Akiniwa,
Fumiyasu Iwahori
et al.

Abstract: An ESR spin probe technique with non‐TEMPO radicals, such as nitronyl nitroxide (NN), benzonitronyl nitroxide (BzNN), and iminonitroxide (IN) radicals, was used for a porous metal‐organic framework (MOF), [(ZnI2)3(TPT)2] (ZnTPT; TPT = tris(4‐pyridyl)‐1,3,5‐triazine), at room temperature. The principal values of g and hyperfine coupling (A) tensors estimated from spectral reproduction were different from those for organic matrices for some of these radicals. These results indicate that host‐guest interactions o… Show more

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