2017
DOI: 10.1007/s10800-017-1117-7
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Electroreduction and solubility of CO2 in methoxy- and nitrile-functionalized imidazolium (FAP) ionic liquids

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Cited by 9 publications
(5 citation statements)
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“…The performance of ILs with cyano (–CN) or methoxy (–OCH 3 ) functionalized imidazolium cations was also evaluated as electrolytes for electrochemical reduction of CO 2 on Pt catalyst. 52 The results indicated that the addition of the functional groups in ILs can reduce the activated energy for the formation of CO 2 ⋅– intermediate. Consistently, the Pt(110) single crystal catalyst also efficiently promoted electrochemical synthesis of HCOOH from CO 2 in [Emim]NTF 2 electrolyte.…”
Section: Main Textmentioning
confidence: 95%
“…The performance of ILs with cyano (–CN) or methoxy (–OCH 3 ) functionalized imidazolium cations was also evaluated as electrolytes for electrochemical reduction of CO 2 on Pt catalyst. 52 The results indicated that the addition of the functional groups in ILs can reduce the activated energy for the formation of CO 2 ⋅– intermediate. Consistently, the Pt(110) single crystal catalyst also efficiently promoted electrochemical synthesis of HCOOH from CO 2 in [Emim]NTF 2 electrolyte.…”
Section: Main Textmentioning
confidence: 95%
“…The results are often inconsistent. However, the most important parameter from the industrial point of view, solubility, is rarely reported [35,43]. Therefore, in this study, we calculated the solubility of individual siloxanes (L2, L3, and D4) in various DESs composed of TPABr as HBA and glycols, i.e., ethylene glycol (EG), glycerol (Gly), triethylene glycol (TriEG), tetraethylene glycol (TEG), and diethylene glycol (DEG), as HBD at various molar ratios (1:3; 1:4; 1:5; 1:6, HBA:HBD).…”
Section: Melting Point Measurementsmentioning
confidence: 99%
“…In general, hole models are based on the statement that the vacancies present at molecular level are randomly distributed [42]. When an ionic mixture melts, the variation in temperature during the melting process produces fluctuations of the local density, which are responsible for the formation of empty spaces [43]. The consequent molecular framework is dynamic and allows, at some specific conditions, the constant movement of the ions with opportune size to fit in the holes, which move by this mechanism all-over the network.…”
Section: Molecular Structure Of Deep Eutectic Systems and Propertiesmentioning
confidence: 99%
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“…The CO 2 reduction efficiency under this condition was 3 orders of magnitude higher than the previously reported catalytic efficiency of Au and Cu-based nanomaterials, thus achieving the efficient conversion of CO 2 . Bruzon et al studied the electroreduction performance of CO 2 in methoxyl and nitrogen-based functionalized imidazolium (FAP) ILs and found that the electric potential required for CO 2 reduction was significantly reduced, and the functional groups −OCH 3 and −CN may effectively reduce the free energy of formation of CO 2 •– . Liu et al prepared silver sulfide nanowire catalysts with a 121 crystal face, and tested the CO 2 reduction performance in [Emim]­[BF 4 ].…”
Section: Roles Of Ils On Ecr Promotionmentioning
confidence: 99%