2021
DOI: 10.26434/chemrxiv-2021-dp7br
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Electrostatic loading and photoredox-based release of molecular cargo from oligoviologen-crosslinked microparticles

Abstract: Although on-demand cargo release has been demonstrated in a wide range of microparticle platforms, many existing methods lack specific loading interactions and/or undergo permanent damage to the microparticle to release the cargo. Here, we report a novel method for electrostatically loading negatively charged molecular cargo in oligoviologen-crosslinked microparticles, wherein the cargo can be released upon activation by visible light. A water-in-oil (W/O) emulsion polymerization method was used to fabricate n… Show more

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