1999
DOI: 10.1002/(sici)1099-0690(199906)1999:6<1471::aid-ejoc1471>3.0.co;2-e
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Electrosynthesis of Aromatic Aldehydes by Palladium-Catalyzed Carbonylation of Aryl Iodides in the Presence of Formic Acid

Abstract: The palladium‐catalyzed electrocarbonylation of aryl halides performed in the presence of formic acid under one atmosphere of carbon monoxide affords aromatic aldehydes in good to high yields.

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Cited by 22 publications
(38 citation statements)
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“…Evidence for the Reversible Formation of a Cationic Palladium-Hydride HPd(PPh 3 ) 2 ؉ in the Oxidative Addition of Acetic or Formic Acid to Pd 0 (PPh 3 ) 4 …”
Section: Resultsmentioning
confidence: 99%
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“…Evidence for the Reversible Formation of a Cationic Palladium-Hydride HPd(PPh 3 ) 2 ؉ in the Oxidative Addition of Acetic or Formic Acid to Pd 0 (PPh 3 ) 4 …”
Section: Resultsmentioning
confidence: 99%
“…The oxidative addition of acetic acid to Pd 0 (PPh 3 ) 4 in DMF has been monitored at 25°C by conductivity measurements. The conductivity κ of a solution of Pd 0 (PPh 3 ) 4 (2 m) increased after addition of n equivalents of acetic acid (n Ͼ 1) and reached a limit ( Figure 1).…”
Section: By Conductivity Measurements In Dmfmentioning
confidence: 99%
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