2024
DOI: 10.1021/acsapm.4c01032
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Endowing Polyurethane with Degradability via a Cleavable Bis(cyclohexanone) Oxalyldihydrazone Structure for Adhesive Detachment

Zhengxiang Zhou,
Qiangqiang Yan,
Yinzhong Guo
et al.

Abstract: Detachable and degradable polymeric adhesives have demonstrated considerable value and significance, accompanying the increasing demands for waste recycling and the ongoing concern for green and sustainable development. Herein, a chain extender containing the bis(cyclohexanone) oxalyldihydrazone structure was introduced into polyurethanes, which achieved efficient degradation in an alkaline environment with the M w decreasing from 41.9 to 4.9 kDa. The shear strength of the linear polyurethane between polycarbo… Show more

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