Energetic 1,2,3,4‐Tetrazines

Insight into the structural and energetic features of substituted triazolofurazans

“…Our research group is focused on developing fundamental methodological principles utilized to design and synthesize novel heterocyclic HEDMs including energetic salts. 11,12 One of the questions that we are very interested in and to which there is no exhaustive answer in the literature is what happens to the structure of N-heterocycle and its properties when N-oxides, N-NO 2 or C(NO 2 ) 2 and other related fragments are introduced. There are separate computational works, mainly devoted to the influence of N-oxide; 13 however, a systematic study involving available experimental data was published only recently and only for covalent structures.…”