2024
DOI: 10.1021/acsomega.4c00349
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Energetic Nitrate-Based Polymer-Bonded Explosives Derived from Sustainable Aza-Michael Reactions

Gayathri Sheela,
Vijayalakshmi Kunduchi Periya,
Santhosh Gopalakrishnan
et al.

Abstract: A novel nontoxic method for processing energetic binder, namely, polyglycidyl nitrate (PGN), using Aza-Michael reactions for deriving high-performance explosive formulations is being reported. The polyol binders used in polymer-bonded explosives (PBX) including PGN are usually cross-linked using isocyanate leading to polyurethane (PU)-based cured solid networks. These reactions require mild reaction conditions and yield good mechanical properties for the PBX but remain challenging due to extraneous reactions o… Show more

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