2021
DOI: 10.1016/j.apcatb.2021.119963
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Engineered carbon supported single iron atom sites and iron clusters from Fe-rich Enteromorpha for Fenton-like reactions via nonradical pathways

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Cited by 358 publications
(92 citation statements)
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“…[ 45 , 46 , 47 ] As the probe reaction, methyl phenyl sulfoxide (PMSO) can be oxidized by high‐valent Fe species to form dimethyl sulfone (PMSO 2 ) via an oxygen‐atom‐transfer process. [ 48 , 49 ] The transformation from PMSO to PMSO 2 can be monitored by HPLC, the existence of high‐valence Fe can thus be confirmed. As shown in Figure S18 (Supporting Information), PMSO cannot be oxidized by PMS alone or with NPC as catalyst.…”
Section: Resultsmentioning
confidence: 95%
See 1 more Smart Citation
“…[ 45 , 46 , 47 ] As the probe reaction, methyl phenyl sulfoxide (PMSO) can be oxidized by high‐valent Fe species to form dimethyl sulfone (PMSO 2 ) via an oxygen‐atom‐transfer process. [ 48 , 49 ] The transformation from PMSO to PMSO 2 can be monitored by HPLC, the existence of high‐valence Fe can thus be confirmed. As shown in Figure S18 (Supporting Information), PMSO cannot be oxidized by PMS alone or with NPC as catalyst.…”
Section: Resultsmentioning
confidence: 95%
“…Usually, in a system dominated by high-valent Fe, the oxidation process will be ended with PMSO converted into PMSO 2 , and further degradation will not happen. [50][51][52] Therefore, we speculate that this process is not dominated by high-valence Fe.…”
Section: •−mentioning
confidence: 99%
“…Tetracycline (TC) is a typical antibiotic used to kill pathogenic bacteria in humans and animals, and has been widely used against commonly occurring infections of the skin and other organs. 1–7 Large amounts of wastewater containing antibiotics are directly discharged into water sources, which poses a massive threat to human health and causes serious environmental problems. 7–11 Thus, it is imperative to explore new control methods and water treatment technologies for removing TC from the water environment.…”
Section: Introductionmentioning
confidence: 99%
“…1–7 Large amounts of wastewater containing antibiotics are directly discharged into water sources, which poses a massive threat to human health and causes serious environmental problems. 7–11 Thus, it is imperative to explore new control methods and water treatment technologies for removing TC from the water environment. In recent years, semiconductor photocatalysis degradation technology has gained widespread interest as a green and environmentally friendly way to degrade organic pollutants in water.…”
Section: Introductionmentioning
confidence: 99%
“… 9 A large number of methods, such as ozonation, biological treatment, ionic exchange, photocatalysis, oxidative process and adsorption have been developed for the removal of organic dyes from water. 10 However, these efforts are always associated with high chemical and energy consumption, as well as costly equipment investment. Therefore, developing more eco-friendly and efficient tactics for the removal of the organic dyes and turning these chemical pollutants into wealth is still a very meaningful and challenging research.…”
Section: Introductionmentioning
confidence: 99%