Enhanced Organocatalytic Processes through an Engineered Acid‐Base Site Bifunctional Pore in a Zirconium Metal‐Organic Framework
José María Moreno,
Rodrigo Gil‐San‐Millan,
Rubén Mas‐Ballesté
et al.
Abstract:This work introduces a robust acid‐base catalytic system based on the zirconium‐based metal‐organic framework (Zr‐MOF) MOF‐808, selected for its open structure, high stability, and low presence of structural defects compared to other Zr‐MOFs. Four bifunctional benzoate ligands bearing free ‐COOH and N‐based groups were introduced into the MOF‐808 using solvent‐assisted ligand exchange methods. Unlike other materials, the acid and base sites in the bifunctional MOF‐808 materials are situated in the same capping… Show more
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