A 2D/2D BiPO 4 /g-C 3 N 4 -B nano-sheet heterojunction photocatalyst was synthesized via a simple coprecipitation method at room temperature using glacial acetic acid as solvent, which showed excellent activity toward the degradation of rhodamine B (RhB).The heterojunction showed much higher e ciency of separation and transfer of photogenerated carriers compared to that of its constituents. Moreover, the spectral response range of BiPO 4 was effectively broadened after the combination of g-C 3 N 4 -B and BiPO 4 . Consequently, a 97.3% degradation of RhB within 25 min by BiPO 4 /g-C 3 N 4 -B heterojunction photocatalyst under visible light irradiation was observed. The difference in work functions of BiPO 4 and g-C 3 N 4 -B was evident from UPS characterization, which led to the bending of the energy band and the establishment of an internal electric eld at the interface of the heterojunction. Therefore, the synthesized direct Z-type BiPO 4 /g-C 3 N 4 -B heterojunction enhanced the oxidation-reduction ability by promoting the effective separation of photogenerated carriers.