Enthalpies, Entropies, and Free Energy Functions of TIF, TIBr, and TII above Room Temperature.

Cubicciotti, Daniel; Eding, Harold

doi:10.1021/je60027a012

Cited by 39 publications

(5 citation statements)

References 4 publications

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“…Numerous x-ray studies of CdS [49,68,98,118,146] have confirmed the high pressure structure as cubic NaCl-type. Most of these studies were performed in situ.…”

Section: Zinc Oxidementioning

confidence: 99%

Behavior of the AB-type compounds at high pressures and high temperatures

Merrill¹

1977

Journal of Physical and Chemical Reference Data

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The results of the published work on the high pressure-high temperature properties of the AB-type compounds have been compiled and evaluated. All pressure studies above the range of 1 kilobar have been included with an. emphasis on the accurate charterization of the solid-solid. phase' boundaries and the experimental melting curves. Whenever x-ray diffraction data are available for the high pressure phases, they have also been reviewed. Phase diagrams are included for all compounds in which measurement of more than one point along the phase boundary was made. This review discusses a total of 87 comp01,lnds and 212 distinct high pressurehigh temperature phases.

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“…Numerous x-ray studies of CdS [49,68,98,118,146] have confirmed the high pressure structure as cubic NaCl-type. Most of these studies were performed in situ.…”

Section: Zinc Oxidementioning

confidence: 99%

Behavior of the AB-type compounds at high pressures and high temperatures

Merrill¹

1977

Journal of Physical and Chemical Reference Data

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“…However, space group P2cm requires there to be two symmetry-independent pairs of anions and cations in 2c x,y, sites (labeled Tl1, Tl2, F1, and F2), this structure being identical to the Pbc2 model of Barlow and Meredith (11) if the ionic coordinates satisfy the conditions y 2 "!y 2 and y $ "!y $ . On increasing temperature a structural transition has been observed at &355 K by di!erential thermal analysis (DTA) (9), drop calorimetry (15), and X-ray di!raction (11) methods. The structure of the high-temperature modi"cation [labeled TlF-I (9)] has been studied by X-ray di!raction and the results are summarized in Table 1.…”

Section: Review Of the Literaturementioning

confidence: 99%

The Crystal Structures of Thallium(I) Fluoride

Berastegui

Hull

2000

Journal of Solid State Chemistry

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“…--Enthalpy measurements above 298 ~ to about 1000~ were measured in a drop calorimeter by the same method as described earlier (12,13). The sample of about 10g of BiF3 was placed in a platinum test tube and the end sealed by crimping and platinum soldering.…”

Section: Properties Of Bif3 1139mentioning

confidence: 99%

Thermodynamic Properties of Bismuth Trifluoride

Cubicciotti

1968

J. Electrochem. Soc.

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Thermodynamic properties were determined for bismuth trifluoride that had been dried by heating in a stream of hydrogen fluoride. The melting point was found to be 649° C. The thermodynamic functions of the gaseous molecule were calculated from estimates of the molecular geometry and vibration frequencies. Heat capacities were measured for the solid and liquid, and the heat (5.16 kcal) and entropy of fusion (5.6 eu) were obtained.The vapor pressure over the solid was measured by a transpiration method. The vapor pressure of BiF3 over the solid is given by logp )(normalmm=−9753T+11.72 An equation for the vapor pressure over the liquid was derived and the boiling point calculated to be 900°C. The enthalpy of sublimation (48.1 kcal/mole) and the entropy of sublimation (46.6 eu) at 298°K were derived from the vapor pressures.The enthalpy of formation of bismuth trifluoride (−215 kcal/mole) was determined by solution calorimetry. The enthalpy of atomization of bismuth trifluoride gas (273 kcal/mole) was calculated from the enthalpy of formation. The derived bismuth‐fluorine bond energy is compared with those of the other group VA halides.

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Enthalpies, Entropies, and Free Energy Functions of TIF, TIBr, and TII above Room Temperature.

Cited by 39 publications

References 4 publications

Behavior of the AB-type compounds at high pressures and high temperatures

Behavior of the AB-type compounds at high pressures and high temperatures

The Crystal Structures of Thallium(I) Fluoride

Thermodynamic Properties of Bismuth Trifluoride

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