The study was conducted in 2 urbanized areas of the Baikal region of Russia. These are the cities of Shelekhov and Tayshet with their suburbs. Aluminum production has been carried out in Shelekhov for over 60 years and in Tayshet for 5 years. The purpose of the study was to determine the pollution of urban soils with toxic elements—Al, F, Be, Li, as well as Cr, Ni, Pb, and so on under the influence of industrial enterprises (aluminum and cable plants, thermal power plants). Also, the purpose of the research was to determine the effect of increased fluorite (F) in the environment on children’s health. Pure aluminum is used much less frequently than in alloys. The addition of various elements (Be, B, Li, Fe, Si, Mg, Mn, Zr, Ag, Pb, Cu, Ni, and others) increases the hardness, density, thermal conductivity, and other properties of the alloys. The area of high F content in urban soil is 15 times higher than the regional context. The maximum content of Na, Be, and Al is 2 to 4 times higher than the regional background. An increased Li content is marked only near aluminum smelters. The F content in urine samples from children living in areas with long-term pollution exposure (Shelekhov) is 1.5 to 2 times higher than in the group of children with a short exposure period (Tayshet).